专利名称 | METHOD FOR PREPARING 2-FLUOROACRYLATE | ||
申请号 | WOCN18072199 | 申请日 | |
公开(公告)号 | WO2019000910A1 | 公开(公告)日 | 2018-01-11 |
申请(专利权)人 | 发明人 | QIU Kunlun; WANG Wenbo; YU Qianjie; LI Botao; LIAN Xiongdong; LI Gongyong | |
专利来源 | 国家知识产权局 | 转化方式 | |
摘要 |
Disclosed is a method for preparing a 2-fluoroacrylate, using the following steps : (1) a vinyl ether with a structure as shown in formula A is mixed with monofluorodichloromethane to obtain a substituted cyclopropane compound with a structure as shown in formula B; (2) the substituted cyclopropane compound with the structure as shown in formula B is mixed with R2OH to obtain an acetal product with a structure as shown in formula C, and the acetal product is then hydrolyzed to obtain a 2-fluoroacrolein with a structure as shown in formula D; or the substituted cyclopropane compound with the structure as shown in formula B is reacted with water for cracking to obtain the 2-fluoroacrolein with the structure as shown in formula D; (3) the 2-fluoroacrolein with the structure as shown in formula D is oxidized to obtain a 2-fluoroacrylic acid with a structure as shown in formula E; and (4) the 2-fluoroacrylic acid with the structure as shown in formula E is mixed with R3OH to obtain a 2-fluoroacrylate with a structure as shown in formula F. |
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