The invention is a polyoxymethylene film and a preparation method. The polyoxymethylene film comprises : 96 to 98 parts by weight of polyoxymethylene resin, 0.5 to 2 parts by weight of nucleating agent, 0.5 to 1 parts by weight of antioxidant, and 0.5 to 1 parts by weight of formaldehyde absorbent. In view of the high crystallinity and fast crystallization rate of polyoxymethylene, blown film process is used to directly blowing the molten mass extruded through a die of a screw extruder to form a blown film bubble. It is easy to form thin neck and easy to break when stretching, so the method is beneficial to form polyoxymethylene film, and has high processing efficiency, and is suitable for industrialization. Copolymerization unit —CH2—CH2—O— is introduced into the molecular chain of polyoxymethylene and its ratio is increased, thereby effectively reducing the crystallization rate of the materials and making it easier to form a film.